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报道了双核铜（Ⅱ）配合物Ｃｕ２（Ｓａｌｅｎ）２（Ｓａｌｅｎ为Ｎ，Ｎ′－二水杨醛乙二胺席夫碱）的合成、表征和晶体结构分析．该晶体属单斜晶系，具有Ｃ２／ｃ（Ｎｏ．１５）空间群，ａ＝２．６５８０（５）ｎｍ，ｂ＝０．６９８６（１）ｎｍ，ｃ＝１．４７１８（３）ｎｍ，β＝９７．６３（３）°，Ｖ＝２．７０８（１）ｎｍ３，Ｚ＝８，Ｄｃ＝１．６１８Ｍｇ／ｍ３，Ｆ（０００）＝１３５２，Ｒ＝０．０８８，ｗＲ＝０．０７３，ＧＯＦ（Ｆ）＝０．８９．该化合物是由两个氧桥桥联的双核铜（Ⅱ）配合物，铜（Ⅱ）离子处于五配位的畸变四方锥配位环境中报道了双核铜（Ⅱ）配合物Ｃｕ２（Ｓａｌｅｎ）２（Ｓａｌｅｎ为Ｎ，Ｎ′－二水杨醛乙二胺席夫碱）的合成、表征和晶体结构分析．该晶体属单斜晶系，具有Ｃ２／ｃ（Ｎｏ．１５）空间群，ａ＝２．６５８０（５）ｎｍ，ｂ＝０．６９８６（１）ｎｍ，ｃ＝１．４７１８（３）ｎｍ，β＝９７．６３（３）°，Ｖ＝２．７０８（１）ｎｍ３，Ｚ＝８，Ｄｃ＝１．６１８Ｍｇ／ｍ３，Ｆ（０００）＝１３５２，Ｒ＝０．０８８，ｗＲ＝０．０７３，ＧＯＦ（Ｆ）＝０．８９．该化合物是由两个氧桥桥联的双核铜（Ⅱ）配合物，铜（Ⅱ）离子处于五配位的畸变四方锥?
The synthesis, characterization and crystal structure analysis of Cu2 (Salen) 2 (Salen is N, N’-bis-salicylaldehyde ethylenediamine Schiff base) was reported. The crystal belongs to the monoclinic system with space group C2 / c (No.15), a = 2.6580 (5) nm, b = 0.6986 β = 97.63 (3) °, V = 2.708 (1) nm3, Z = 8, Dc = 1.618Mg / m3, F (000) = 1352, R = 0.088, wR = 0.073 , GOF (F) = 0.89. The compound is a dinuclear copper (Ⅱ) complex bridged by two oxygen bridges. The copper (Ⅱ) complex Cu2 (Salen) 2 (Salen is N, N’-bis-salicylaldehyde ethylenediamine Schiff base) synthesis, characterization and crystal structure analysis. The crystal belongs to the monoclinic system with space group C2 / c (No.15), a = 2.6580 (5) nm, b = 0.6986 β = 97.63 (3) °, V = 2.708 (1) nm3, Z = 8, Dc = 1.618Mg / m3, F (000) = 1352, R = 0.088, wR = 0.073 , GOF (F) = 0.89. The compound is a dinuclear copper (Ⅱ) complex bridged by two oxygen bridges and the copper (Ⅱ) ion is in a five-coordinate distorted tetragon cone.