【摘 要】
：
The reactions of [CptRhCl((-Cl)]2 (1) (Cpt = tBu2C5H3) with Li2E2C2B10H10 (E = S, Se) lead to the green 16-electron dichalcogenolate complexes CptRh(E2C2B10H10)
【机 构】
：
Laboratory of Molecular Catalysis and Innovative Material
论文部分内容阅读
The reactions of [CptRhCl((-Cl)]2 (1) (Cpt = tBu2C5H3) with Li2E2C2B10H10 (E = S, Se) lead to the green 16-electron dichalcogenolate complexes CptRh(E2C2B10H10) [E = S(2a), Se(2b)]. The 16-electron complexes 2a and 2b can take up two-electron donor ligands such as tert-butyl isonitrile and carbon monoxide to give the 18-electron dichalcogenolate derivatives Cpt(L)(E2C2B10H10) [L = tBuNC, E = S(3a), Se(3b); L = CO, E = S(4a), Se(4b)]. The molecular structures of complexes 2a and 3a were determined by X-ray crystal structure analysis. The molecular structure of 16- electron complex 2a shows the pseudoaromatic system in IrSe2C2 five numbered ring.
其他文献
151 in situ analyses of oxygen isotopes were carried out by ion micro-probe for zircons from 8 localities of HP-UHP metamorphic rocks including eclogites in the
The stability of differential-algebraic equations (DAEs) was analyzed using singularity induced bifurcation (SIB) with one parameter. This kind of bifurcation a
Previous work studied a production system including multiple stations (or workshops) consisting of an entry station, a set of workstations, an exit station, and
发展电动汽车产业不仅有利于提高能源安全保障能力、促进节能减排,还有利于促进产业升级。电网企业的参与有利于推动电动汽车产业的发展。运营模式的制定是充换电服务网络构
In this paper the qualitative analysis methods of planar autonomous systems and numerical simu-lation are used to investigate the peaked wave solutions of CH-r
Graphs for the design of networks or electronic circuits are usually weighted and the spectrum of weighted graphs are often analyzed to solve problems. This pap
The numerical solution of functional differential equations with a proportional delay is considered. The stability of general linear methods for linear systems
This paper studies the e-ergodicity for discrete-time recurrent Markov chains. It proves that thee-order deviation matrix exists and is finite if and only if th
D structures of velocity and temperature are obtained using the data of P-wave veloc-ity and heat flow in North China (105E—124E, 30N—42N). Taking into accoun
Fluorinated amorphous carbon films (a-C:F) were prepared at different temperaturesusing a microwave electron cyclotron resonance chemical vapor deposition (ECR-