为揭示历代越窑青瓷的制釉技术及发展规律、探讨南宋时期的类官窑青瓷与传统越窑青瓷的差异,从而探讨以配釉技术为载体的中国古代瓷器生产技术的发展规律及传播线路,由浙江省博物馆与故宫博物院合作,采用便携式荧光能谱仪对越窑不同时期的青瓷标本和南宋时期的类官窑青瓷标本的釉层元素组成进行了无损分析。结果表明从东汉、唐代、五代、北宋直至南宋不同时期的越窑青瓷釉的元素组成变化不大,即历代越窑青瓷釉为高钛、高铁的瓷石加草木灰的二元配方,并保持连续了近千年。相比之下,南宋时期的类官窑青瓷的釉料配方中使用了一种钛、铁含量极低的原料,这表明南宋类官窑青瓷的制釉技术有别于传统越窑青瓷。本项研究还表明采用便携式X射线荧光能谱仪可在无损的条件下分析研究古陶瓷的釉层元素组成,这对辅助揭示古陶瓷的釉料配方和发展规律起着重要作用。 In order to reveal the glaze technology and development law of Yue celadon in the past Dynasties and to explore the difference between the celadon kiln in the Southern Song Dynasty and the traditional Yue kiln celadon in order to discuss the development rules and propagation routes of porcelain production technology in ancient China with glaze technology as carrier , By the cooperation between Zhejiang Provincial Museum and the National Palace Museum, portable elemental spectroscopy was used to analyze the elemental composition of the glazed layer of celadon from different periods of Yueyao celadon and Southern Kiangsi celadon. The results show that the elemental compositions of Yue celadon enamel from Yuehan, Tang Dynasty, Five Dynasties, Northern Song Dynasty and Southern Song Dynasty changed little, that is, the celadon enamel of the Yue Dynasty was the binary formula of high-titanium and high-iron porcelain stone plus ash, For nearly a thousand years. In contrast, the Southern Song Dynasty kilogram celadon celadon glaze formula used a titanium, iron content is very low raw materials, indicating that Southern Song Dynasty kiln celadon celadon glaze technology is different from the traditional Yue kiln celadon. The present study also shows that the elemental composition of the glaze layer of ancient ceramics can be analyzed and studied in a non-destructive manner using a portable X-ray fluorescence spectrometer, which plays an important role in assisting in revealing the formulation and development of the glaze of ancient ceramics.