过渡金属与希土的多核配合物由于具有特殊的光、电、磁等方面的性质，已经引起人们广泛的兴趣。但是由于镧系元素离子较大的各向异性效应以及与ｄ 区过渡金属间弱相互作用的缘故，有关的研究报道还不多见。本文报道以四齿席夫碱合锌配合物（ＺｎＳａｌｅｎ）和ＥｕＬ３ ·２Ｈ２Ｏ为原料，合成了新的铕（Ⅲ）－锌（Ⅱ）双核配合物，并对其性质和结构进行了研究 Multinuclear complexes of transition metals and rare earths have attracted widespread interest due to their special properties of light, electricity and magnetism. However, due to the large anisotropy effect of lanthanide ions and the weak interaction with the transition metal in d region, the relevant research reports are rare. In this paper, a new Eu (Ⅲ) -zinc (Ⅱ) binuclear complex was synthesized by using the four-atom Schiff base zinc complexes (ZnSalen) and EuL3 · 2H2O as raw materials, and their properties and structures were studied