手性氮、膦配体是一类新型的多齿配位体 ,可提供氮和膦两种供电子基团 ;这些氮、膦供电子基团分别作为软、硬供电子体优先与低氧化态的后过渡金属及亲氧的过渡金属螯合 .这类配体有更多的反应特点 ,它们可以控制目的产物的配位数及立体化学结构 ,表现出丰富的配位化学性质 .此? Chiral nitrogen, phosphine ligands are a new class of multidentate ligands that provide two electron donating groups, nitrogen and phosphine. These nitrogen and phosphine electron donating groups, as soft and hard electron donors, respectively, preferentially and lowly oxidize State of the transition metal and oxy-oxygen transition metal chelation. These ligands have more reaction characteristics, they can control the coordination number of the target product and the three-dimensional chemical structure, showing a wealth of coordination chemistry.