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采用Ni(Ⅱ)盐和氨基甲磺酸缩3,5-二氯水杨醛席夫碱(H2L)以及1,10-邻菲咯林(phen)在甲醇和水溶液中合成了三元配合物[Ni(Ⅱ)(C8H7O4NCl2S)(Phen)(H2O)]3(1),通过元素分析、红外光谱对配合物1进行了表征,并通过X射线衍射测定了其结构。结构解析表明,配合物1属三斜晶系,空间群P墿,晶胞参数为:a=1.5640(3)nm,b=1.5650(3)nm,c=1.5650(3)nm;α=94.84(3)°,β=94.73(3)°,γ=94.80(3)°,V=3.7881(13)nm3,Z=6,Dc=1.420g.cm-3,F(000)=1602,μ=1.100mm-1,最终偏差因子(对I>2σ(I)的衍射点),R1=0.0769,ωR2=0.1306,对全部衍射点R1=0.1323,ωR2=0.1468,ω-1=[σ2(Fo)2+(0.1977P)2],P=(Fo2+2Fc2)/3。配合物1通过卤卤作用(Cl-Cl0.3574(8)nm)堆积成3D无限层状结构。
Ternary complexes [Ni (Ⅱ)] and sulfamic acid Schiff base (H2L) and 1,10-phenanthroline (phen) were synthesized in methanol and aqueous solution (Ⅱ) (C8H7O4NCl2S) (Phen) (H2O)] 3 (1). The complex 1 was characterized by elemental analysis and infrared spectroscopy. The structure of the complex was characterized by X-ray diffraction. Structure analysis shows that the complex 1 belongs to the triclinic system with space group P 墿. The unit cell parameters are: a = 1.5640 (3) nm, b = 1.5650 (3) nm, c = 1.5650 (3) °, β = 94.73 (3) °, γ = 94.80 (3) °, V = 3.7881 (13) nm3, Z = 6, Dc = 1.420g.cm-3, = 1.100mm-1, the final deviation factor (the diffraction point for I> 2σ (I)), R1 = 0.0769 and ωR2 = 0.1306 and for all diffraction points R1 = 0.1323, ωR2 = 0.1468 and ω-1 = [σ2 (Fo ) 2+ (0.1977P) 2], P = (Fo2 + 2Fc2) / 3. Complex 1 is deposited into a 3D infinite layered structure by the action of halogens (Cl-Cl0.3574 (8) nm).